Yerry Mina's header put Everton back in front on the stroke of halftime and James rounded off an excellent individual display with two second half goals.
Khachanov won the pair's previous encounter in Paris - at 2018 Paris Masters, when the Russian claimed a straight-set win in the final to clinch the biggest title of his career until now.
In another highly-anticipated fixture between Inter and Lazio, Lautaro Martinez put Inter ahead in the 30th minute, while the Biancocelesti got the game back on level terms 10 minutes after the break with Sergej Milinkovic-Savic's powering header.
"They played great and showed their value on the court, which led to our victory," Li commented.
The goalless draw follows another 0-0 away to newly promoted Huesca in midweek and even though Luis Suarez was in the starting 11 for the second time in four days, he looked to be lacking match-fitness as Atletico produced just two shots on target in the entire 90 minutes.
Fueled by Wei's six points in a row, Inner Mongolia widened the gap back to seven points, and they used a 22-13 second quarter to build a 13-point advantage at halftime.
It looked like Bayern was on the way to an easy victory but Hertha Berlin turned up the intensity and halved the deficit only seven minutes later when Cordoba headed home Matheus Cunha's free kick.
Although it is still very early days, the signs are much better at FC Barcelona than many expected before the season started. Ronald Koeman's team has won its first two games with ease, netting a total of seven goals without conceding and the image on the pitch has been much better than the side that looked sad and tired during Quique Setien's time in charge.
"The ITTF and CTTA remain committed to ensuring that the highest safety measures are implemented to protect everyone involved in the events," said the world table tennis governing body. Enditem
James, 29, has also impressed in his opening three matches for Everton in the Premier League following his summer move from Real Madrid.
Zhejiang outscored 52-37 at the interval, which proved to be a key part of their victory. Dong Ke'er made six 3-pointers to score 26 points. Huang Jiali shot 11 of 14 from the field for 26 points.